The redox conditions of soil may have significant consequences for the mobility of metallic elements (ME), but unlike pH, very few studies have investigated this parameter. A procedure was established to study the solubilization of ME from soil samples in various reducing conditions using a batch method and sodium ascorbate solutions. The change in redox potential from +410 to +10 mV was studied from four contaminated soil samples (designated A-D) of different origins and compositions. The results showed that ME mobilization greatly increased with decreasing redox potential within a limited and very sensitive range. Depending on the soil sample studied, various sensitive ranges of potentials were obtained (A, 220-345 mV; B, 280-365 mV; C, 260-360 mV; and D, 240-380 mV), and the induced percentages of ME mobilization varied (i.e., maximal values for Zn: A, 45%; B, 59%; C, 53%; and D, 58%). The results could be explained by the combined effect of potential and pH decrease on ME-carrying phases; in particular, Fe and Mn (oxy)hydroxides.