Abstract
A new strategy for mixed biaryl synthesis has been developed using the hypervalent iodine(III) reagents. The unique reactivities of the sigma-heteroaryl iodine(III) intermediates generated in situ are the key element for the unusual metal catalyst-free transformations and strict control of the product selectivities.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Benzene Derivatives / chemical synthesis
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Benzene Derivatives / chemistry*
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Iodine / chemistry
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Naphthalenes / chemical synthesis
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Naphthalenes / chemistry*
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Onium Compounds / chemistry
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Oxidation-Reduction
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Pyrroles / chemical synthesis
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Pyrroles / chemistry*
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Thiophenes / chemical synthesis
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Thiophenes / chemistry*
Substances
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Benzene Derivatives
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Naphthalenes
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Onium Compounds
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Pyrroles
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Thiophenes
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Iodine