Polycapillary-optics-based micro-XANES and micro-EXAFS at a third-generation bending-magnet beamline

J Synchrotron Radiat. 2009 Mar;16(Pt 2):237-46. doi: 10.1107/S0909049508043306. Epub 2009 Jan 16.

Abstract

A focusing system based on a polycapillary half-lens optic has been successfully tested for transmission and fluorescence micro-X-ray absorption spectroscopy at a third-generation bending-magnet beamline equipped with a non-fixed-exit Si(111) monochromator. The vertical positional variations of the X-ray beam owing to the use of a non-fixed-exit monochromator were shown to pose only a limited problem by using the polycapillary optic. The expected height variation for an EXAFS scan around the Fe K-edge is approximately 200 microm on the lens input side and this was reduced to approximately 1 microm for the focused beam. Beam sizes (FWHM) of 12-16 microm, transmission efficiencies of 25-45% and intensity gain factors, compared with the non-focused beam, of about 2000 were obtained in the 7-14 keV energy range for an incoming beam of 0.5 x 2 mm (vertical x horizontal). As a practical application, an As K-edge micro-XANES study of cucumber root and hypocotyl was performed to determine the As oxidation state in the different plant parts and to identify a possible metabolic conversion by the plant.

Publication types

  • Evaluation Study
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Capillary Action
  • Equipment Design
  • Equipment Failure Analysis
  • Lenses*
  • Magnetics / instrumentation*
  • Miniaturization
  • Reproducibility of Results
  • Sensitivity and Specificity
  • Spectrometry, X-Ray Emission / instrumentation*
  • Synchrotrons / instrumentation*