Quantitative formation of [4]pseudorotaxanes from two rods and two bis-macrocycles incorporating porphyrinic plates between the rings

Chem Commun (Camb). 2009 Apr 7:(13):1706-8. doi: 10.1039/b901482a. Epub 2009 Feb 26.

Abstract

[4]pseudorotaxanes consisting of two very large coordinating bis-macrocycles and rigid rods incorporating two side-by-side chelates have been obtained quantitatively utilising the gathering and threading effect of copper(I); the assemblies obtained are several nanometres long and they contain two face-to-face zinc porphyrins which will be used to complex various organic substrates.