Symmetry breaking of graphene monolayers by molecular decoration

Phys Rev Lett. 2009 Apr 3;102(13):135501. doi: 10.1103/PhysRevLett.102.135501. Epub 2009 Mar 31.

Abstract

Aromatic molecules can effectively exfoliate graphite into graphene monolayers, and the resulting graphene monolayers sandwiched by the aromatic molecules exhibit a pronounced Raman G-band splitting, similar to that observed in single-walled carbon nanotubes. Raman measurements and calculations based on the force-constant model demonstrate that the absorbed aromatic molecules are responsible for the G-band splitting by removing the energy degeneracy of in-plane longitudinal and transverse optical phonons at the Gamma point.