Abstract
United in effort: The combined application of iminium (Im) and enamine (En) catalysts can effect a range of valuable asymmetric transformations including 1,2-hydroamination, -hydro-oxidation, and -amino-oxidation of olefins (see picture). An enantioselective organocascade catalysis was also applied in the synthesis of a complex natural product.
Publication types
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Research Support, N.I.H., Extramural
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Research Support, Non-U.S. Gov't
MeSH terms
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Alkenes / chemistry*
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Amination
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Catalysis
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Oxidation-Reduction
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Sesquiterpenes / chemical synthesis*
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Sesquiterpenes / chemistry
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Sesquiterpenes, Guaiane
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Stereoisomerism
Substances
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Alkenes
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Sesquiterpenes
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Sesquiterpenes, Guaiane
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aromadendranediol