Estimation of the breathing energy of flexible MOFs by combining TGA and DSC techniques

Sabine Devautour-Vinot; Guillaume Maurin; François Henn; Christian Serre; Thomas Devic; Gérard Férey

doi:10.1039/b822834e

Estimation of the breathing energy of flexible MOFs by combining TGA and DSC techniques

Chem Commun (Camb). 2009 May 21:(19):2733-5. doi: 10.1039/b822834e. Epub 2009 Mar 20.

Authors

Sabine Devautour-Vinot¹, Guillaume Maurin, François Henn, Christian Serre, Thomas Devic, Gérard Férey

Affiliation

¹ Institut Charles Gerhardt Montpellier, PMDP, UMR 5253 CNRS-UM2-ENSCM-UM1, 34095, Montpellier cedex 05, France. [email protected]

PMID: 19532937
DOI: 10.1039/b822834e

Abstract

The energetics of the breathing phenomenon of MIL-53(Cr) have been estimated through a combined TGA and DSC water desorption analysis of the rigid MIL-47(V) and flexible MIL-53(Cr) and MIL-53(Fe) systems.