High sensitive determination of zinc with novel water-soluble small molecular fluorescent sensor

Anal Chim Acta. 2009 Aug 11;647(2):215-8. doi: 10.1016/j.aca.2009.06.026. Epub 2009 Jun 17.

Abstract

A high sensitive method of quantitative analysis for the determination of zinc in the nutrition supplements has been developed by using a novel water-soluble fluorescent sensor HQ3: (8-pyridylmethyloxy-2-methyl-quinoline). Under the optimized condition of 67 mM phosphate buffer, pH 7.4, and 5% (v/v) DMSO, the zinc concentration showed good linear relationship with fluorescence intensity in the range of 7.5 x 10(-8) to 2.5 x 10(-5) M with the detection limit of 1.5 x 10(-8) M. HQ3 exhibited high selectivity to zinc comparing with other metal ions except for cadmium. The developed analytical method was successfully used for determining the content of zinc in a real sample of zinc gluconate solution of Sanchine.

Publication types

  • Research Support, Non-U.S. Gov't
  • Validation Study

MeSH terms

  • Dietary Supplements / analysis*
  • Edetic Acid / chemistry
  • Fluorescent Dyes / chemistry*
  • Gluconates / analysis
  • Hydrogen-Ion Concentration
  • Linear Models
  • Quinolines / chemistry*
  • Sensitivity and Specificity
  • Spectrometry, Fluorescence / methods*
  • Water
  • Zinc / analysis*

Substances

  • Fluorescent Dyes
  • Gluconates
  • Quinolines
  • Water
  • Edetic Acid
  • quinoline
  • Zinc
  • gluconic acid