Quaternary tin(IV) antimony(III) sulfide decorated with lanthanum(III) ethylenediamine complexes: [La(en)4SbSnS5]2 x 0.5 H2O

Mei-Ling Feng; Dong Ye; Xiao-Ying Huang

doi:10.1021/ic901044k

Quaternary tin(IV) antimony(III) sulfide decorated with lanthanum(III) ethylenediamine complexes: [La(en)4SbSnS5]2 x 0.5 H2O

Inorg Chem. 2009 Sep 7;48(17):8060-2. doi: 10.1021/ic901044k.

Authors

Mei-Ling Feng¹, Dong Ye, Xiao-Ying Huang

Affiliation

¹ State Key Laboratory of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou 350002, People's Republic of China.

PMID: 19642620
DOI: 10.1021/ic901044k

Abstract

A quaternary tin(IV) antimony(III) sulfide decorated by lanthanum(III) ethylenediamine complexes, namely, [La(en)(4)SbSnS(5)](2) x 0.5 H(2)O (1; en = ethylenediamine), has been solvothermally synthesized and structurally, thermally, and optically characterized. Its structure features an isolated hexanuclear molecule of [La(en)(4)SbSnS(5)](2). The intermolecule hydrogen-bond interactions result in a three-dimensional supramolecular network, which remains intact upon dehydration.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Antimony / chemistry*
Crystallography, X-Ray
Ethylenediamines / chemistry*
Hydrogen Bonding
Lanthanum / chemistry*
Macromolecular Substances / chemical synthesis
Macromolecular Substances / chemistry
Models, Molecular
Organometallic Compounds / chemical synthesis*
Organometallic Compounds / chemistry
Sulfides / chemistry*
Tin Compounds / chemistry*

Substances

Ethylenediamines
Macromolecular Substances
Organometallic Compounds
Sulfides
Tin Compounds
tin sulfide
ethylenediamine
Lanthanum
Antimony
antimony trisulfide