Assembly of a 1D coordination polymer through in situ formation of a new ligand by double C-C coupling on CHCl3 under solvothermal conditions

Guo-Bi Li; Jun-Min Liu; Zhi-Quan Yu; Wei Wang; Cheng-Yong Su

doi:10.1021/ic9011263

Assembly of a 1D coordination polymer through in situ formation of a new ligand by double C-C coupling on CHCl3 under solvothermal conditions

Inorg Chem. 2009 Sep 21;48(18):8659-61. doi: 10.1021/ic9011263.

Authors

Guo-Bi Li¹, Jun-Min Liu, Zhi-Quan Yu, Wei Wang, Cheng-Yong Su

Affiliation

¹ MOE Laboratory of Bioinorganic and Synthetic Chemistry, State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China.

PMID: 19689104
DOI: 10.1021/ic9011263

Abstract

A rare in situ metal/ligand reaction has been observed during the assembly of a manganese-coordination polymer under solvothermal conditions, which leads to double C-C coupling on CHCl(3) involving cleavage of three C-Cl bonds and the formation of two new C-C bonds at the same carbon center.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Carbon / chemistry*
Chloroform / chemistry*
Ligands
Magnetic Resonance Spectroscopy
Manganese / chemistry*
Methylation
Molecular Structure
Organometallic Compounds / chemistry*
Polymers / chemistry*
Pyridines / chemistry
Solvents / chemistry
Spectrometry, Mass, Electrospray Ionization
Temperature

Substances

Ligands
Organometallic Compounds
Polymers
Pyridines
Solvents
Manganese
Carbon
Chloroform
pyridine