Rediscovering the Schulze-Hardy rule in competitive adsorption to an air-water interface

Langmuir. 2009 Sep 1;25(17):10045-50. doi: 10.1021/la9009724.

Abstract

The ratio of divalent to monovalent ion concentration necessary to displace the surface-active protein, albumin, by lung surfactant monolayers and multilayers at an air-water interface scales as 2(-6), the same concentration dependence as the critical flocculation concentration (CFC) for colloids with a high surface potential. Confirming this analogy between competitive adsorption and colloid stability, polymer-induced depletion attraction and electrostatic potentials are additive in their effects; the range of the depletion attraction, twice the polymer radius of gyration, must be greater than the Debye length to have an effect on adsorption.

Publication types

  • Research Support, N.I.H., Extramural
  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Adsorption
  • Air*
  • Albumins / chemistry
  • Colloids / chemistry*
  • Hydrogen-Ion Concentration
  • Lipid Bilayers / chemistry
  • Models, Statistical
  • Polyethylene Glycols / chemistry
  • Polymers / chemistry
  • Pressure
  • Static Electricity
  • Surface Properties
  • Surface Tension
  • Surface-Active Agents
  • Water / chemistry*

Substances

  • Albumins
  • Colloids
  • Lipid Bilayers
  • Polymers
  • Surface-Active Agents
  • Water
  • Polyethylene Glycols