Environment-sensitive stabilisation of silver nanoparticles in aqueous solutions

J Colloid Interface Sci. 2009 Nov 15;339(2):317-24. doi: 10.1016/j.jcis.2009.07.065. Epub 2009 Aug 6.

Abstract

We describe the preparation and characterisation of inorganic-organic hybrid block copolymer silver nanoparticles via the preparation of spherical multi-responsive polymeric micelles of poly(N-methyl-2-vinyl pyridinium iodide)-block-poly(ethylene oxide), P2MVP(38)-b-PEO(211) and poly(acrylic acid)-block-poly(isopropyl acrylamide), PAA(55)-b-PNIPAAm(88) in the presence of AgNO(3). Hence, the P2MVP and PAA segments were employed to fix Ag(+) ions within the micellar core (25 degrees C) or shell (60 degrees C), while the PEO segments ensured spontaneous reduction of Ag(+) ions into metallic Ag, as well as colloidal stabilisation. Spherical and elongated composite core-shell(-corona) nanoparticles (CNPs) were formed containing several small, spherical silver nanoparticles within the micellar core or shell. As the co-assembly of the oppositely charged copolymers into micelles is electrostatically driven, the CNPs can be destabilised by, for example, addition of simple salts, i.e., the CNPs are stimuli responsive. CNP size and morphology control can be achieved via the preparation protocol. For example, heating to 60 degrees C, i.e., above the PNIPAAm LCST, results in core-shell-corona CNPs with the Ag-NPs situated in the aggregate shell.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Cryoelectron Microscopy
  • Drug Stability
  • Micelles
  • Microscopy, Electron, Transmission
  • Nanoparticles* / chemistry
  • Polyethylene Glycols
  • Silver*
  • Solutions
  • Vinyl Compounds

Substances

  • Micelles
  • Solutions
  • Vinyl Compounds
  • poly(N-methyl-2-vinyl pyridinium iodide)-b-poly(ethylene oxide)
  • Silver
  • Polyethylene Glycols