Abstract
Conformational factors in self-assembled chiral tetraamide macrocycles control their gas-phase enantioselectivity towards the ethyl ester of naphthylalanine to levels typical of enzymes.
MeSH terms
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Alanine / analogs & derivatives
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Alanine / chemistry
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Catalysis
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Gases / chemistry*
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Hydrogen Bonding
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Kinetics
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Macrocyclic Compounds / chemistry*
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Models, Molecular
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Molecular Conformation*
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Molecular Structure
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Spectrometry, Mass, Electrospray Ionization / methods
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Stereoisomerism
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Thermodynamics
Substances
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Gases
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Macrocyclic Compounds
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Alanine