Atomic-scale heterogeneity of a multicomponent bulk metallic glass with excellent glass forming ability

Phys Rev Lett. 2009 Aug 14;103(7):075502. doi: 10.1103/PhysRevLett.103.075502. Epub 2009 Aug 12.

Abstract

We report the atomic structure of a multicomponent Cu45Zr45Ag10 bulk metallic glass investigated by state-of-the-art experimental and computational techniques. In comparison with a binary Cu50Zr50 metallic glass, Zr-rich interpenetrating clusters centered by paired and stringed Ag atoms and Cu-rich icosahedra are widely observed in the ternary Cu45Zr45Ag10 alloy. The atomic-scale heterogeneity caused by chemical short- and medium-range order is found to play a key role in stabilizing the liquid phase and in improving the glass forming ability of the multicomponent alloy.