Wave-packet dynamics in chains with delayed electronic nonlinear response

Phys Rev Lett. 2009 Aug 28;103(9):096401. doi: 10.1103/PhysRevLett.103.096401. Epub 2009 Aug 24.

Abstract

We study the dynamics of one electron wave packet in a chain with a nonadiabatic electron-phonon interaction. The electron-phonon coupling is taken into account in the time-dependent Schrödinger equation by a delayed cubic nonlinearity. In the limit of an adiabatic coupling, the self-trapping phenomenon occurs when the nonlinearity parameter exceeds a critical value of the order of the bandwidth. We show that a weaker nonlinearity is required to produce self-trapping in the regime of short delay times. However, this trend is reversed for slow nonlinear responses, resulting in a reentrant phase diagram. In slowly responding media, self-trapping only takes place for very strong nonlinearities.