High efficiency flexible ITO-free polymer/fullerene photodiodes

Phys Chem Chem Phys. 2006 Sep 7;8(33):3904-8. doi: 10.1039/b607016g.

Abstract

We report efficient polymer photodiodes fabricated on flexible polyethyleneterephthalate (PET) substrates. The PET substrates were coated with a layer of poly(3,4-ethylene-dioxythiophene): polystyrenesulfonate (PEDOT:PSS) that was lithographically patterned to define the anode structure. A blend of poly(3-hexylthiophene) (P3HT) and 1-(3-methoxycarbonyl)-propyl-1-phenyl-(6,6)C61 (PCBM) was then spin-coated from a 1 : 1 mixture by weight of the two components in dichlorobenzene, and the device was completed by vacuum deposition of an aluminium electrode in vacuum. The resulting photodiodes had short-circuit quantum efficiencies of 45% and peak power efficiencies of 3%, which compare favourably with values for similar devices fabricated on rigid indium tin oxide (ITO) coated glass substrates.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Electrochemistry
  • Electrodes
  • Fullerenes / chemistry*
  • Models, Molecular
  • Polyethylene Terephthalates / chemistry*
  • Spectrophotometry
  • Tin Compounds / chemistry*

Substances

  • 1-(3-methoxycarbonyl)propyl-1-phenyl-(6,6)C61
  • Fullerenes
  • Polyethylene Terephthalates
  • Tin Compounds
  • indium tin oxide