Abstract
Reactions of amines with nitric oxide (NO) at high pressures form diverse NO donor species, highly dependent on the precursor structure. While monoamine precursors favor the formation of N-diazeniumdiolates in high yield, polyamines exhibit competitive formation of N-nitrosamines and diazeniumdiolates, resulting in mixed products containing significant percentages of undesired N-nitroso compounds.
Publication types
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Research Support, N.I.H., Extramural
MeSH terms
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Amines / chemistry*
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Azo Compounds / chemical synthesis*
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Azo Compounds / chemistry
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Molecular Structure
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Nitric Oxide / chemistry*
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Nitric Oxide Donors / chemistry*
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Nitrosamines / chemical synthesis*
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Nitrosamines / chemistry
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Nitroso Compounds / chemical synthesis
Substances
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Amines
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Azo Compounds
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Nitric Oxide Donors
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Nitrosamines
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Nitroso Compounds
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diazeniumdiolate
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Nitric Oxide