In vivo monitor oxidative burst induced by Cd2+ stress for the oilseed rape (Brassica napus L.) based on electrochemical microbiosensor

Phytochem Anal. 2010 Mar-Apr;21(2):192-6. doi: 10.1002/pca.1178.

Abstract

Introduction: Since the mechanism of Cd(2+) stress for plants is not clear, an in vivo method to monitor Cd(2+) stress for plants is necessary. However, oxidative burst (OB) is a signal messenger in the process of Cd(2+) stress for plants.

Objective: To establish an electrochemical method with poly-o-phenylenediamine and Pt microparticle modified Pt electrode (POPD-Pt-MP-Pt) as a microbiosensor for the in vivo detection of oxidative burst induced by Cd(2+) stress in oilseed rape (Brassica napus L.).

Methodology: The optimal fabrication of POPD-Pt-MP-Pt biosensor was achieved. Electrochemical signal was collected by amperometry.

Results: After oilseed rape was exposed to 84.9 mM CdCl(2) stress, three oxidative bursts were observed in oilseed rape by amperometry at 3.3 h, 8.4 h and 13.2 h, respectively. However, there was no obvious signal observed in the controlled assay.

Conclusion: This contribution presents the in vivo monitoring of the OB process induced by Cd(2+) stress in oilseed rape by POPD-Pt-MP-Pt microbiosensor in real-time. The novel electrochemical microbiosensor not only facilitates the real-time study in plant self-defence response to the adverse environment such as Cd(2+) stress, but also provides an effective tool for probing the self-defence mechanism in plants.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Biosensing Techniques / instrumentation
  • Biosensing Techniques / methods
  • Brassica napus / drug effects*
  • Brassica napus / metabolism*
  • Cadmium / toxicity*
  • Cadmium Chloride / toxicity
  • Cations, Divalent
  • Electrochemical Techniques / instrumentation
  • Electrochemical Techniques / methods*
  • Electrodes
  • Phenylenediamines / chemistry*
  • Platinum / chemistry*
  • Respiratory Burst / drug effects*
  • Stress, Physiological / drug effects

Substances

  • Cations, Divalent
  • Phenylenediamines
  • poly(o-phenylenediamine)
  • Cadmium
  • Platinum
  • Cadmium Chloride