Validation data for HPLC/FLD determinations of ochratoxin A in red paprika and black pepper adopting a one-step clean-up procedure

Food Addit Contam Part A Chem Anal Control Expo Risk Assess. 2010 Feb;27(2):249-54. doi: 10.1080/19440040903384182.

Abstract

Validation data for the determination of ochratoxin A (OTA) in two spice matrices, red paprika and black pepper, were obtained for samples prepared with a simplified single-step clean-up column. Extracts of finely ground samples of red paprika and black pepper were prepared and applied to a Mycosep 229 Ochra clean-up column. The purified extract was then subjected to HPLC/FLD analysis. The relative standard deviation for repeatability (RSDr) of the method was 11.8% for red paprika and 9.9% for black pepper. The limit of detection (LOD) value (three times the noise) was estimated as corresponding to the response of an extract derived from a blank matrix (previously washed) and spiked at 1.0 microg kg(-1). The limit of quantitation (LOQ) (three times LOD) was 3.0 microg kg(-1). The performance of the one-step column clean-up procedure appears to be a suitable alternative to commonly used clean-up techniques and allows the precise determination of OTA in two complex matrices.

Publication types

  • Research Support, Non-U.S. Gov't
  • Validation Study

MeSH terms

  • Capsicum / chemistry*
  • Chromatography, High Pressure Liquid / standards*
  • Limit of Detection
  • Ochratoxins / analysis*
  • Piper nigrum / chemistry*
  • Reproducibility of Results
  • Spectrometry, Fluorescence / methods*
  • Spectrometry, Mass, Electrospray Ionization
  • Tandem Mass Spectrometry

Substances

  • Ochratoxins
  • ochratoxin A