Towards an asymmetric synthesis of the bacterial peptide deformylase (PDF) inhibitor fumimycin

Org Biomol Chem. 2009 Dec 21;7(24):5059-62. doi: 10.1039/b916372g. Epub 2009 Oct 19.

Abstract

Studies towards the synthesis of the bacterial peptide deformylase (PDF) inhibitor fumimycin are reported. The synthetic approach features an organocatalytic access to the alpha,alpha-disubstituted amino acid unit and results in the synthesis of an advanced intermediate which already contains all functionalities of fumimycin.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Amidohydrolases / antagonists & inhibitors*
  • Amino Acids / chemistry
  • Benzofurans / chemical synthesis*

Substances

  • Amino Acids
  • Benzofurans
  • fumimycin
  • Amidohydrolases
  • peptide deformylase