From July to September 2008, a measurement was made on the physical and chemical properties of bulk precipitation and throughfall in five main forest types, i.e., larch plantation (LP), Fraxinus rhynchophylla stand (FR), mixed forest stand (MF), Korean pine plantation (KP), and Mongolian oak stand (MO), of secondary forest ecosystem in montane regions of eastern Liaoning Province, China. Comparing with bulk precipitation, the throughfall in the five forest types was significantly acidified (P < 0.05), and the acidification degree was in the order of KP > LP > MF > MO > FR. The conductivity and total dissolved solids of the throughfall increased significantly (P < 0.05), and were in the sequence of MO > FR > LP > MF > KP. The dissolved oxygen concentration of the throughfall lowered significantly (P < 0.05), with the rank of KP > MF > FR > MO > LP, while the Cl- concentration increased significantly, ranked as LP > MO > MF > FR > KP. The NO3-concentrations of the throughfall in FR, MO and MF were higher, while those in LP and KP were lower than that of the bulk precipitation.