Thrombin generation-based assays to measure the activity of the TFPI-protein S pathway in plasma from normal and protein S-deficient individuals

J Thromb Haemost. 2010 Apr;8(4):750-8. doi: 10.1111/j.1538-7836.2010.03743.x. Epub 2010 Jan 17.

Abstract

Background: Protein S acts as a cofactor for full-length tissue factor pathway inhibitor (TFPI) in the downregulation of thrombin formation.

Objective: To develop a functional test to measure the activity of the TFPI-protein S system in plasma.

Methods/patients: Using calibrated automated thrombography, we quantified the activity of the TFPI-protein S system in plasma by measuring thrombin generation in the absence and presence of neutralizing antibodies against protein S or TFPI. Moreover, we designed an enzyme-linked immunosorbent assay (ELISA) to determine the level of full-length TFPI in plasma. The performance of these assays was examined in plasma from 85 normal individuals and from 35 members of protein S-deficient families.

Results: The ratio of thrombin peaks determined in the absence and presence of anti-protein S antibodies (protein S ratio = 0.5 in normal plasma) is a measure of the TFPI cofactor activity of protein S, whereas the ratio of thrombin peaks determined in the absence and presence of anti-TFPI antibodies (TFPI ratio = 0.25 in normal plasma) is a measure of the overall activity of the TFPI-protein S system. Protein S and TFPI ratios were elevated in protein S-deficient individuals, indicating an impairment of the TFPI-protein S system. Both ratios correlated well with full-length TFPI levels, which were significantly lower in protein S-deficient patients than in normal family members.

Conclusions: Functional assays for the TFPI-protein S system and an ELISA for full-length TFPI were developed. These assays show that the activity of the TFPI-protein S anticoagulant pathway is impaired in individuals with congenital protein S deficiency.

Publication types

  • Research Support, Non-U.S. Gov't
  • Validation Study

MeSH terms

  • Amino Acid Sequence
  • Antibodies, Neutralizing
  • Automation, Laboratory
  • Biomarkers / blood
  • Blood Coagulation Tests* / standards
  • Calibration
  • Case-Control Studies
  • Enzyme-Linked Immunosorbent Assay* / standards
  • Female
  • Humans
  • Lipoproteins / blood*
  • Lipoproteins / immunology
  • Male
  • Molecular Sequence Data
  • Predictive Value of Tests
  • Protein S / immunology
  • Protein S / metabolism*
  • Protein S Deficiency / blood
  • Protein S Deficiency / diagnosis*
  • Reproducibility of Results
  • Thrombin / metabolism*

Substances

  • Antibodies, Neutralizing
  • Biomarkers
  • Lipoproteins
  • Protein S
  • lipoprotein-associated coagulation inhibitor
  • Thrombin