Pd-catalyzed oxidative cross-coupling of N-tosylhydrazones with arylboronic acids

Xia Zhao; Jing Jing; Kui Lu; Yan Zhang; Jianbo Wang

doi:10.1039/b925590g

Pd-catalyzed oxidative cross-coupling of N-tosylhydrazones with arylboronic acids

Chem Commun (Camb). 2010 Mar 14;46(10):1724-6. doi: 10.1039/b925590g. Epub 2010 Feb 3.

Authors

Xia Zhao¹, Jing Jing, Kui Lu, Yan Zhang, Jianbo Wang

Affiliation

¹ Beijing National Laboratory of Molecular Sciences (BNLMS) and Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871, China.

PMID: 20177629
DOI: 10.1039/b925590g

Abstract

The Pd-catalyzed reaction of N-tosylhydrazones and arylboronic acids provides olefin derivatives. This oxidative cross-coupling is suggested to proceed through a migratory insertion process of a Pd carbene intermediate.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Boronic Acids / chemistry*
Catalysis
Hydrazones / chemistry*
Kinetics
Oxidation-Reduction
Palladium / chemistry*

Substances

Boronic Acids
Hydrazones
Palladium