Facile synthesis of indole- or benzofuran-fused benzo[a]carbazole-1,4-diones using a tandem two-step reaction sequence

Mol Divers. 2011 Feb;15(1):91-9. doi: 10.1007/s11030-010-9241-x. Epub 2010 Mar 14.

Abstract

An efficient three-step approach was developed to assemble indole- or benzofuran-fused benzocarbazole-1,4-diones in 42-53% overall yield. This approach includes AgOAc-promoted oxidative cyclization of 2,6-di-bromocyclohexene-1,4-dione with indol-3-ylpropanoid acid, condensation of the resulting bromocarbazole intermediates with phenols or anilines, followed by Pd(OAc)-catalyzed cyclization. Such convenient synthetic protocol and the novelty of the corresponding products will largely assist our drug design and development program.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Benzofurans / chemistry*
  • Carbazoles / chemical synthesis*
  • Carbazoles / chemistry*
  • Catalysis
  • Cyclization
  • Indoles / chemistry*

Substances

  • Benzofurans
  • Carbazoles
  • Indoles
  • carbazole
  • benzofuran