Proline-containing cyclopeptides from the marine sponge Phakellia fusca

J Nat Prod. 2010 Apr 23;73(4):650-5. doi: 10.1021/np9008267.

Abstract

Four new cyclopeptides, phakellistatins 15-18 (2-5), together with five known cyclopeptides, phakellistatin 13 (1), hymenistatin 1, and hymenamides G, H, and J, were isolated from the South China Sea sponge Phakellia fusca. Their structures were elucidated by HR-ESIMS, NMR, and MALDI-TOF/TOF sequence analysis. The absolute configurations of the amino acid residues of 2-5 were assigned to be l by enantioselective HPLC analysis.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Animals
  • Marine Biology
  • Molecular Structure
  • Nuclear Magnetic Resonance, Biomolecular
  • Peptides, Cyclic / chemistry
  • Peptides, Cyclic / isolation & purification*
  • Porifera / chemistry*
  • Proline / chemistry*
  • Stereoisomerism

Substances

  • Peptides, Cyclic
  • hymenistatin
  • phakellistatin 13
  • Proline