Cobalt-containing polyimides for moisture sensing and absorption

ACS Appl Mater Interfaces. 2009 May;1(5):1041-4. doi: 10.1021/am9000198.

Abstract

A modified polyimide has been created that both senses and absorbs moisture. The material was prepared by introducing cobalt(II) chloride, a well-known moisture sensing and absorbing metal salt, into a polyimide. The final polymer was found to be fully cured, retaining the metal without any leeching, and was thermally stable. Furthermore, the material underwent a visible color change when exposed to moisture and reverted back to the original color when subsequently dried. The total moisture absorbed was measured with a quartz crystal microbalance. The amount of moisture absorption was found to be proportional to the relative humidity, and the modified polymer was found to have up to 3 times greater moisture absorption compared to the unmodified polymer.

Publication types

  • Evaluation Study
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Absorption
  • Cobalt / chemistry*
  • Colorimetry / instrumentation*
  • Crystallization / methods
  • Equipment Design
  • Equipment Failure Analysis
  • Imides / chemistry*
  • Materials Testing
  • Micro-Electrical-Mechanical Systems / instrumentation*
  • Porosity
  • Water / analysis*
  • Water / chemistry*

Substances

  • Imides
  • Water
  • Cobalt