Cs(9)[(gamma-PW(10)O(36))(2)Ru(4)O(5)(OH)(H(2)O)(4)], a new all-inorganic, soluble catalyst for the efficient visible-light-driven oxidation of water

Claire Besson; Zhuangqun Huang; Yurii V Geletii; Sheri Lense; Kenneth I Hardcastle; Djamaladdin G Musaev; Tianquan Lian; Anna Proust; Craig L Hill

doi:10.1039/b926064a

Cs(9)[(gamma-PW(10)O(36))(2)Ru(4)O(5)(OH)(H(2)O)(4)], a new all-inorganic, soluble catalyst for the efficient visible-light-driven oxidation of water

Chem Commun (Camb). 2010 Apr 28;46(16):2784-6. doi: 10.1039/b926064a. Epub 2010 Feb 25.

Authors

Claire Besson¹, Zhuangqun Huang, Yurii V Geletii, Sheri Lense, Kenneth I Hardcastle, Djamaladdin G Musaev, Tianquan Lian, Anna Proust, Craig L Hill

Affiliation

¹ Institut Parisien de Chimie Moléculaire, UMR CNRS 7201, UPMC Univ. Paris 06, Case 42, 4 place Jussieu, 75005 Paris, France.

PMID: 20369182
DOI: 10.1039/b926064a

Abstract

The tetraruthenium-substituted polyoxometalate Cs(9)[(gamma-PW(10)O(36))(2)Ru(4)O(5)(OH)(H(2)O)(4)] was synthesized and structurally, spectroscopically and electrochemically characterized; it was shown to be a catalyst for visible-light-induced water oxidation.