Abstract
A novel heterodifunctional phosphinite imidazolium salt was synthesized and reacted with Ag(I) to afford an unusual tetrasilver cubane-type cluster with two P-NHC ligands bridging between the Ag(I) centres of opposite Ag(2)I(2) faces.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Crystallography, X-Ray
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Heterocyclic Compounds / chemistry*
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Imidazoles / chemical synthesis
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Imidazoles / chemistry
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Ligands
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Methane / analogs & derivatives*
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Methane / chemistry
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Models, Molecular
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Molecular Structure
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Organometallic Compounds / chemical synthesis*
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Organometallic Compounds / chemistry
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Phosphines / chemical synthesis
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Phosphines / chemistry*
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Salts / chemical synthesis
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Salts / chemistry
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Silver / chemistry*
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Stereoisomerism
Substances
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Heterocyclic Compounds
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Imidazoles
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Ligands
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Organometallic Compounds
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Phosphines
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Salts
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carbene
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Silver
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Methane