Tri-, deca- and dodecanuclear Co(III)-pyrazolate metallacycles

Chem Commun (Camb). 2010 Apr 21;46(15):2569-71. doi: 10.1039/b920486e. Epub 2010 Mar 12.

Abstract

Reactions of a Co(III) salt with pyrazoles in the presence of a base have yielded metallacyclic {Co(3)}, {Co(10)} and {Co(12)} species whose structural characterization points to a parallel between analogous carboxylate and pyrazolate motifs.