Total synthesis of the proposed structure of iriomoteolide-1a

Chem Commun (Camb). 2010 Jul 14;46(26):4770-2. doi: 10.1039/c0cc00628a. Epub 2010 May 18.

Abstract

The total synthesis of the proposed structure of iriomoteolide-1a has been accomplished via a Yamaguchi esterification and ring closing metathesis sequence between the C(7)-C(23) and newly synthesized Z-alkenoic acid C(1)-C(6) fragments. The spectral data of the synthetic 1, however, is at odds with data reported for the natural product, thus bringing into question the original structural assignment.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Esterification
  • Macrolides / chemical synthesis*
  • Macrolides / chemistry
  • Molecular Conformation

Substances

  • Macrolides
  • iriomoteolide-1a