Kinetic analysis of novel mono- and multivalent VHH-fragments and their application for molecular imaging of brain tumours

Br J Pharmacol. 2010 Jun;160(4):1016-28. doi: 10.1111/j.1476-5381.2010.00742.x.

Abstract

Background and purpose: The overexpression of epidermal growth factor receptor (EGFR) and its mutated variant EGFRvIII occurs in 50% of glioblastoma multiforme. We developed antibody fragments against EGFR/EGFRvIII for molecular imaging and/or therapeutic targeting applications.

Experimental approach: An anti-EGFR/EGFRvIII llama single-domain antibody (EG(2)) and two higher valency format constructs, bivalent EG(2)-hFc and pentavalent V2C-EG(2) sdAbs, were analysed in vitro for their binding affinities using surface plasmon resonance and cell binding studies, and in vivo using pharmacokinetic, biodistribution, optical imaging and fluorescent microscopy studies.

Key results: Kinetic binding analyses by surface plasmon resonance revealed intrinsic affinities of 55 nM and 97 nM for the monovalent EG(2) to immobilized extracellular domains of EGFR and EGFRvIII, respectively, and a 10- to 600-fold increases in apparent affinities for the multivalent binders, V2C-EG(2) and EG(2)-hFc, respectively. In vivo pharmacokinetic and biodistribution studies in mice revealed plasma half-lives for EG(2), V2C-EG(2) and EG(2)-hFc of 41 min, 80 min and 12.5 h, respectively, as well as a significantly higher retention of EG(2)-hFc compared to the other two constructs in EGFR/EGFRvIII-expressing orthotopic brain tumours, resulting in the highest signal in the tumour region in optical imaging studies. Time domain volumetric optical imaging fusion with high-resolution micro-computed tomography of microvascular brain network confirmed EG(2)-hFc selective accumulation/retention in anatomically defined tumour regions.

Conclusions: Single domain antibodies can be optimized for molecular imaging applications by methods that improve their apparent affinity and prolong plasma half-life and, at the same time, preserve their ability to penetrate tumour parenchyma.

Publication types

  • Comparative Study
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Animals
  • Antibodies / metabolism
  • Antibody Affinity
  • Brain Neoplasms / blood supply
  • Brain Neoplasms / diagnosis*
  • Brain Neoplasms / metabolism
  • Brain Neoplasms / ultrastructure
  • Cell Line, Tumor
  • ErbB Receptors / immunology
  • ErbB Receptors / metabolism*
  • Glioblastoma / blood supply
  • Glioblastoma / diagnosis*
  • Glioblastoma / metabolism
  • Glioblastoma / ultrastructure
  • Half-Life
  • Humans
  • Immobilized Proteins / metabolism
  • Immunoglobulin Heavy Chains / immunology
  • Immunoglobulin Heavy Chains / metabolism*
  • Immunoglobulin Variable Region / immunology
  • Immunoglobulin Variable Region / metabolism*
  • Kinetics
  • Male
  • Mice
  • Mice, Nude
  • Molecular Imaging / methods
  • Molecular Weight
  • Tomography, Optical / methods
  • Whole Body Imaging / methods
  • X-Ray Microtomography / methods

Substances

  • Antibodies
  • Immobilized Proteins
  • Immunoglobulin Heavy Chains
  • Immunoglobulin Variable Region
  • epidermal growth factor receptor VIII
  • EGFR protein, human
  • ErbB Receptors