Abstract
A palladium-catalyzed reductive cross-coupling of 1,3-dienes with boronic esters in which a pi-allyl Pd species is generated directly from a 1,3-diene via a Pd-catalyzed aerobic alcohol oxidation is reported. Both the scope of the process and the origin of a highly selective 1,2-addition are discussed.
Publication types
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Research Support, N.I.H., Extramural
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Research Support, Non-U.S. Gov't
MeSH terms
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Benzene Derivatives / chemistry*
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Boron Compounds / chemistry*
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Catalysis
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Esters / chemistry
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Oxidation-Reduction
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Palladium / chemistry*
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Polyenes / chemistry*
Substances
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Benzene Derivatives
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Boron Compounds
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Esters
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Polyenes
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Palladium