Accelerating high quality bioanalytical LC/MS/MS assays using fused-core columns

J Chromatogr B Analyt Technol Biomed Life Sci. 2010 Sep 1;878(25):2307-13. doi: 10.1016/j.jchromb.2010.06.032. Epub 2010 Jul 3.

Abstract

High quality, ultra-fast bioanalytical LC/MS/MS methods were developed using short columns packed with fused-core particles and high (1.0-3.0 mL/min) flow rates. For more than two years, at flow rates up to 3.0 mL/min, using 0.33 min non-ballistic gradients, these methods were shown to provide comparable or better performance than slower assays for accuracy, precision, sensitivity, specificity, and ruggedness, and met all criteria required by the bioanalytical regulatory guidance.

MeSH terms

  • Chromatography, Liquid / methods*
  • Complex Mixtures / chemistry
  • High-Throughput Screening Assays / methods*
  • Peptides / analysis
  • Pressure
  • Reproducibility of Results
  • Sensitivity and Specificity
  • Tandem Mass Spectrometry / methods*

Substances

  • Complex Mixtures
  • Peptides