Schisanartane nortriterpenoids with diverse post-modifications from Schisandra propinqua

J Nat Prod. 2010 Aug 27;73(8):1337-43. doi: 10.1021/np100144d.

Abstract

Twenty-one highly oxygenated nortriterpenoids with a schisanartane skeleton were isolated from the stems of Schisandra propinqua var. propinqua. These nortriterpenoids featured a polycyclic framework composed of 7/8/5 consecutive carbocycles, which were organized by similar 5/5/7/5/7/5 rings A-F and varied oxygen-containing rings G and H. A biosynthetic classification of these compounds is proposed on the basis of their diverse post-modifications.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Drug Screening Assays, Antitumor
  • Drugs, Chinese Herbal / chemistry
  • Drugs, Chinese Herbal / isolation & purification*
  • Drugs, Chinese Herbal / pharmacology
  • HT29 Cells
  • Humans
  • Molecular Structure
  • Oxygen / chemistry
  • Plant Stems / chemistry
  • Schisandra / chemistry*
  • Triterpenes / chemistry
  • Triterpenes / isolation & purification*
  • Triterpenes / pharmacology

Substances

  • Drugs, Chinese Herbal
  • Triterpenes
  • schisanartane
  • Oxygen