Glyoxal-methylglyoxal cross-reactions in secondary organic aerosol formation

Environ Sci Technol. 2010 Aug 15;44(16):6174-82. doi: 10.1021/es101225q.

Abstract

Glyoxal (G) and methylglyoxal (MG) are potentially important secondary organic aerosol (SOA) precursors. Previous studies of SOA formation by G and MG have focused on either species separately; however, G and MG typically coexist in the atmosphere. We studied the formation of secondary organic material in aqueous aerosol mimic mixtures containing G and MG with ammonium sulfate. We characterized the formation of light-absorbing products using UV-vis spectrophotometry. We found that absorption at 280 nm can be described well using models for the formation of light-absorbing products by G and MG in parallel. Pendant drop tensiometry measurements showed that surface tension depression by G and MG in these solutions can be modeled as a linear combination of the effects of G and MG alone. Product species were identified using chemical ionization mass spectrometry with a volatilization flow tube inlet (Aerosol CIMS). Peaks consistent with G-MG cross-reaction products were observed, accounting for a significant fraction of detected product mass, but most peaks could be attributed to self-reaction. We conclude that cross-reactions contribute to SOA mass from uptake of G and MG, but they are not required to accurately model the effects of this process on aerosol surface tension or light absorption.

Publication types

  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Absorption
  • Aerosols / chemistry*
  • Kinetics
  • Light
  • Mass Spectrometry
  • Pyruvaldehyde / chemistry*
  • Spectrophotometry, Ultraviolet
  • Surface Tension
  • Time Factors
  • Water / chemistry

Substances

  • Aerosols
  • Water
  • Pyruvaldehyde