Abstract
A Brønsted acid differentiated metal catalyzed hydrogenation has been developed. A combinatorial variation of chiral triflylamides with achiral metal complexes results in a highly active catalyst for the asymmetric reduction.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Acids / chemistry*
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Amides / chemistry
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Catalysis
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Hydrogenation
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Iridium / chemistry*
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Kinetics
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Molecular Structure
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Organometallic Compounds / chemistry*
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Quinolines / chemical synthesis*
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Quinolines / chemistry
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Stereoisomerism
Substances
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Acids
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Amides
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Organometallic Compounds
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Quinolines
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Iridium