Ion pair receptors

Chem Soc Rev. 2010 Oct;39(10):3784-809. doi: 10.1039/c002694h. Epub 2010 Aug 24.

Abstract

Compared with simple ion receptors, which are able to bind either a cation or an anion, ion pair receptors bearing both a cation and an anion recognition site offer the promise of binding ion pairs or pairs of ions strongly as the result of direct or indirect cooperative interactions between co-bound ions. This critical review focuses on the recent progress in the design of ion pair receptors and summarizes the various binding modes that have been used to accommodate ion pairs (110 references).

Publication types

  • Research Support, N.I.H., Extramural
  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, Non-P.H.S.
  • Review

MeSH terms

  • Calixarenes / chemistry
  • Crystallography, X-Ray
  • Ions / chemistry*
  • Lewis Acids / chemistry
  • Molecular Conformation
  • Oxides / chemistry
  • Phosphines / chemistry
  • Sulfoxides / chemistry

Substances

  • Ions
  • Lewis Acids
  • Oxides
  • Phosphines
  • Sulfoxides
  • Calixarenes