We apply polarization resolved photoluminescence spectroscopy to measure the spin polarization of a two dimensional electron gas in perpendicular magnetic field. We find that the splitting between the σ+ and σ- polarizations exhibits a sharp drop at ν=5/2 and is equal to the bare Zeeman energy, which resembles the behavior at even filling factors. We show that this behavior is consistent with filling factor ν=5/2 being unpolarized.