Abstract
We show that a redox active {Fe(4)S(4)}(2+)-cubane assembly covalently bound within a cysteinyl-alkylammonium functionalised polypyrrole can be modified with a diiron dithiolate carbonyl unit to give an artificial hydrogenase H-cluster framework confined within the polymer matrix.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Electrodes
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Hydrogenase / chemistry*
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Hydrogenase / metabolism
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Iron-Sulfur Proteins / chemistry*
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Iron-Sulfur Proteins / metabolism
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Oxidation-Reduction
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Polymers / chemistry*
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Pyrroles / chemistry*
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Spectroscopy, Fourier Transform Infrared
Substances
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Iron-Sulfur Proteins
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Polymers
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Pyrroles
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polypyrrole
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iron hydrogenase
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Hydrogenase