Tetra-n-butyl-ammonium iodido(pyrrolidine-1-carbodithio-ato-κS,S')(tris-tert-butoxy-silanethiol-ato-κS)cadmate(II)

Acta Crystallogr Sect E Struct Rep Online. 2008 May 21;64(Pt 6):m832. doi: 10.1107/S1600536808014888.

Abstract

In the anion of the title compound, (C(16)H(36)N)[Cd(C(5)H(8)NS(2))(C(12)H(27)O(3)SSi)I], the Cd atom is four-coordinated by S,S'-chelating dithio-carbamate, S-donating silanethiol-ate and iodide ligands in a distorted tetrahedral environment . Inter-molecular C-H⋯ S and C-H⋯I inter-actions between cations and anions are present. Two C atoms of a tert-butyl group are disordered over two positions; the site occupancies are ca 0.65 and 0.35.