Iron(III) chloride-tandem catalysis for a one-pot regioselective protection of glycopyranosides

Chem Commun (Camb). 2011 Feb 21;47(7):2146-8. doi: 10.1039/c0cc04398b. Epub 2011 Jan 4.

Abstract

Tandem catalysis by using iron(III) chloride hexahydrate leads to carbohydrate building blocks displaying an orthogonal protecting group pattern as illustrated by the regioselective protection of trehalose and maltose disaccharides.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Catalysis
  • Chlorides / chemistry*
  • Ferric Compounds / chemistry*
  • Glucosides / chemical synthesis
  • Glucosides / chemistry*
  • Maltose / chemical synthesis
  • Maltose / chemistry*
  • Stereoisomerism
  • Trehalose / chemical synthesis
  • Trehalose / chemistry*

Substances

  • Chlorides
  • Ferric Compounds
  • Glucosides
  • Maltose
  • Trehalose
  • ferric chloride