A convergent synthesis of the C1-C16 segment of goniodomin A via palladium-catalyzed organostannane-thioester coupling

Org Lett. 2011 Mar 4;13(5):1106-9. doi: 10.1021/ol1031409. Epub 2011 Feb 10.

Abstract

A convergent synthesis of the C1-C16 segment of goniodomin A, an actin-targeting marine polyether macrolide natural product, has been achieved via a 2-fold application of palladium-catalyzed organostannane-thioester coupling.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Actins / metabolism
  • Catalysis
  • Esters
  • Ethers / chemical synthesis*
  • Ethers / chemistry
  • Ethers / pharmacology
  • Macrolides / chemical synthesis*
  • Macrolides / chemistry
  • Macrolides / pharmacology
  • Molecular Structure
  • Organotin Compounds / chemistry*
  • Palladium / chemistry*

Substances

  • Actins
  • Esters
  • Ethers
  • Macrolides
  • Organotin Compounds
  • goniodomin A
  • Palladium