Efficient monophosphorus ligands for palladium-catalyzed Miyaura borylation

Org Lett. 2011 Mar 18;13(6):1366-9. doi: 10.1021/ol2000556. Epub 2011 Feb 14.

Abstract

In combination with the Bedford Pd precursor, the new biaryl monophosphorus ligand 5 was efficient for palladium-catalyzed Miyaura borylation of sterically hindered aryl bromides at low catalyst loadings.

MeSH terms

  • Boron Compounds / chemical synthesis*
  • Boron Compounds / chemistry*
  • Catalysis
  • Hydrocarbons, Brominated / chemistry*
  • Ligands
  • Molecular Structure
  • Organophosphorus Compounds / chemical synthesis
  • Organophosphorus Compounds / chemistry*
  • Palladium / chemistry*

Substances

  • Boron Compounds
  • Hydrocarbons, Brominated
  • Ligands
  • Organophosphorus Compounds
  • Palladium