A novel allylic transfer reaction of chirally modified 2-borylbutadiene: synthesis of chiral homoallenyl alcohols

Chem Commun (Camb). 2011 Apr 7;47(13):3811-3. doi: 10.1039/c0cc05751g. Epub 2011 Feb 14.

Abstract

An enantioselective synthesis of the homoallenyl alcohols was achieved from the reaction of chiral 2-borylbutadiene with aldehydes through an allylic transfer reaction in good yields and enantioselectivities.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Alcohols / chemical synthesis
  • Alcohols / chemistry*
  • Aldehydes / chemical synthesis
  • Aldehydes / chemistry*
  • Butadienes / chemical synthesis
  • Butadienes / chemistry*
  • Stereoisomerism

Substances

  • Alcohols
  • Aldehydes
  • Butadienes