Stability-indicating HPLC assays for the determination of piritramide and droperidol in PCA solution

J Clin Pharm Ther. 2011 Apr;36(2):161-5. doi: 10.1111/j.1365-2710.2010.01169.x. Epub 2010 Aug 13.

Abstract

What is known and objective: A mixture of morphine and droperidol is a well-established antiemetic for reducing the risk of postoperative nausea and vomiting. A mixture of piritramide and droperidol has not yet been evaluated in this context. Our objectives were to develop a high-performance liquid chromatographic assay for piritramide and droperidol in 0·9% saline, and to establish their stability under defined storage conditions.

Methods: The separation and assay of both drugs were attempted by high performance liquid chromatography (HPLC) using a RP-select B column and a mobile phase of 57:43% v/v methanol-monosodium phosphate solution 0·05 M at a flow rate of 1·2 mL/min. UV detection at 205 and 246 nm for piritramide and droperidol were used, respectively.

Results and discussion: The HPLC method was successful. Linearity was shown for piritramide from 0·075 to 0·013 mg/mL and for droperidol from 0·8 to 0·2 mg/mL. The intra- and inter-day relative standard deviation (RSD, %) was 0·27% and 0·54% for piritramide and droperidol, respectively. The two drugs were stable for at least 72 h when stored under ambient light at room temperature.

What is new and conclusion: Seventy-five milligrams piritramide and 2·5 mg droperidol diluted to 50 ml with 0·9% saline should be suitable for clinical use. At this dilution, a Dipidolor(®) and Xomolix(®), mixture, was stable when stored under ambient light exposure at room temperature for at least 72 h.

MeSH terms

  • Analgesia, Patient-Controlled*
  • Analgesics, Opioid / analysis*
  • Antiemetics / analysis*
  • Chromatography, High Pressure Liquid
  • Droperidol / analysis*
  • Drug Stability
  • Humans
  • Pharmaceutical Solutions / analysis
  • Pirinitramide / analysis*
  • Postoperative Nausea and Vomiting / chemically induced
  • Postoperative Nausea and Vomiting / drug therapy*
  • Postoperative Nausea and Vomiting / prevention & control*

Substances

  • Analgesics, Opioid
  • Antiemetics
  • Pharmaceutical Solutions
  • Pirinitramide
  • Droperidol