Elastic torsion effects in magnetic nanoparticle diblock-copolymer structures

J Phys Condens Matter. 2010 Sep 1;22(34):346008. doi: 10.1088/0953-8984/22/34/346008. Epub 2010 Aug 10.

Abstract

Magnetic properties of thin composite films, consisting of non-interacting polystyrene-coated γ-Fe(2)O(3) (maghemite) nanoparticles embedded into polystyrene-block-polyisoprene P(S-b-I) diblock-copolymer films are investigated. Different particle concentrations, ranging from 0.7 to 43 wt%, have been used. The magnetization measured as a function of external field and temperature shows typical features of anisotropic superparamagnets including a hysteresis at low temperatures and blocking phenomena. However, the data cannot be reconciled with the unmodified Stoner-Wohlfarth-Néel theory. Applying an appropriate generalization we find evidence for either an elastic torque being exerted on the nanoparticles by the field or a broad distribution of anisotropy constants.

MeSH terms

  • Anisotropy
  • Biophysics / methods
  • Elasticity
  • Magnetics*
  • Materials Testing
  • Models, Statistical
  • Nanoparticles / chemistry*
  • Physics / methods
  • Polymers / chemistry*
  • Temperature

Substances

  • Polymers