Structural insights into the architecture and allostery of full-length AMP-activated protein kinase

Structure. 2011 Apr 13;19(4):515-22. doi: 10.1016/j.str.2011.01.018.

Abstract

AMP-activated protein kinase (AMPK) is a heterotrimeric complex composed of α catalytic subunit, β scaffolding subunit, and γ regulatory subunit with critical roles in maintaining cellular energy homeostasis. However, the molecular architecture of the intact complex and the allostery associated with the adenosine binding-induced regulation of kinase activity remain unclear. Here, we determine the three-dimensional reconstruction and subunit organization of the full-length rat AMPK (α1β1γ1) through single-particle electron-microscopy. By comparing the structures of AMPK in ATP- and AMP-bound states, we are able to visualize the sequential conformational changes underlying kinase activation that transmits from the adenosine binding sites in the γ subunit to the kinase domain of the α subunit. These results not only make substantial revision to the current model of AMPK assembly, but also highlight a central role of the linker sequence of the α subunit in mediating the allostery of AMPK.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • AMP-Activated Protein Kinases / chemistry*
  • AMP-Activated Protein Kinases / genetics
  • AMP-Activated Protein Kinases / metabolism
  • Adenosine Monophosphate / chemistry
  • Adenosine Monophosphate / metabolism
  • Adenosine Triphosphate / chemistry
  • Adenosine Triphosphate / metabolism
  • Allosteric Site*
  • Animals
  • Binding Sites / drug effects
  • Biocatalysis
  • Catalytic Domain
  • Crystallography, X-Ray
  • Microscopy, Electron
  • Models, Molecular
  • Mutation
  • Protein Binding
  • Protein Multimerization*
  • Protein Structure, Quaternary*
  • Protein Subunits / chemistry
  • Protein Subunits / genetics
  • Protein Subunits / metabolism
  • Rats

Substances

  • Protein Subunits
  • Adenosine Monophosphate
  • Adenosine Triphosphate
  • AMP-Activated Protein Kinases