Self-assembly and conductivity of hydrogen-bonded oligothiophene nanofiber networks

Chem Commun (Camb). 2011 May 28;47(20):5702-4. doi: 10.1039/c1cc10809c. Epub 2011 Apr 18.

Abstract

Symmetric oligothiophene derivatives containing hydrogen bond forming segments create self-supporting organogels consisting of self-assembled 1D nanostructures at low concentrations. Hydrogen bond formation and π-π stacking were both found to be crucial for the formation of conductive supramolecular networks of 1D nanostructures.

Publication types

  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Electric Conductivity
  • Hydrogen Bonding
  • Nanofibers / chemistry*
  • Solvents / chemistry
  • Spectrophotometry, Ultraviolet
  • Thiophenes / chemistry*

Substances

  • Solvents
  • Thiophenes