Facile and unified approach to skeletally diverse, privileged scaffolds

Org Lett. 2011 May 20;13(10):2590-3. doi: 10.1021/ol200709h. Epub 2011 Apr 22.

Abstract

A novel strategy has been developed to generate a diverse array of privileged scaffolds from readily available tetrahydropyridine precursors that may be prepared by a multicomponent assembly process followed by a ring-closing metathesis. The functionality embedded in these key intermediates enables their facile elaboration into more complex structures of biological relevance by a variety of ring-forming processes and refunctionalizations.

Publication types

  • Research Support, N.I.H., Extramural
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Chemistry, Organic / methods*
  • Cyclization
  • Heterocyclic Compounds / chemical synthesis*
  • Heterocyclic Compounds / chemistry
  • Molecular Structure
  • Pyridines / chemistry*

Substances

  • Heterocyclic Compounds
  • Pyridines