Plasmonic nanohybrid with ultrasmall Ag nanoparticles and fluorescent dyes

ACS Nano. 2011 May 24;5(5):3536-41. doi: 10.1021/nn102717z. Epub 2011 May 2.

Abstract

We investigate a hybrid nanocomposite combining fluorescent dyes and ultrasmall (<3 nm) silver nanocrystals in a block copolymer micelle. Although the metal nanoparticles are significantly smaller than the electromagnetic skin depth, we observe a modification of the exciton lifetime and the nonradiative energy transfer among the dyes. This behavior is absent in a control experiment with dyes whose energetic levels are far from the plasmonic resonance, establishing the plasmonic nature of the interaction.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Crystallization / methods*
  • Fluorescent Dyes / chemistry*
  • Gold / chemistry*
  • Macromolecular Substances / chemistry
  • Materials Testing
  • Molecular Conformation
  • Nanostructures / chemistry*
  • Nanostructures / ultrastructure*
  • Particle Size
  • Surface Plasmon Resonance / methods*
  • Surface Properties

Substances

  • Fluorescent Dyes
  • Macromolecular Substances
  • Gold